| Viertelfinal, Viertelfinals - Hinspiele | 01. April 2014 |
| 92' | Sosa | |
| 80' | Diego | |
| 77' | Turan Rodriguez | |
Neymar (1:1) | 71' | |
| 70' | Villa Sosa | |
Fabregas Sanchez | 68' | |
Alba | 58' | |
| 56' | Diego (0:1) | |
Iniesta | 56' | |
| 52' | Juanfran | |
| 44' | Turan | |
| 38' | Gabi | |
| 30' | Diego Costa Diego | |
| 19' | Koke | |
Piqué Bartra | 12' |